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染发剂产品质量解读
 
 
 
 
 

今日关注:染发剂

出场专家:国家化妆品质量监督检验中心(广州)技术研发部  谢文缄

 

产品简介

染发剂是给头发染色的一种化妆品。染发剂分为暂时性染发剂、半永久性染发剂、永久性染发剂。暂时性染发剂是一种只需要用香波洗涤一次就可除去在头发上着色的染发剂。半永久性染发剂一般是指能耐6-12次香波洗涤才退色,半永久性染发剂涂于头发上,停留20-30分钟后,用水冲洗,即可使头发上色。永久性染发剂使用的染料大分子是在头发纤维内通过染料中间体和偶合剂小分子反应生成,因此,在洗涤时,形成的染料大分子是不容易通过毛发纤维的孔径被冲洗。

 

关键指标

1、重金属元素。重金属元素铅、砷、汞是染发剂中有毒物质。汞离子能干扰皮肤内酪氨酸变成黑色素的过程,汞及汞的化合物都可以穿过皮肤的屏障,造成汞中毒,出现大量的黑斑;砷及其化合物都有毒性,皮肤如大量吸收砷可引起皮炎、色素沉积等皮肤病,最终导致皮肤癌;过量的铅被皮肤吸收会危害人体健康,如影响造血系统、神经系统、肾脏、胃肠道、心血管等功能。因此,染发剂中的铅、砷、汞指标限量非常重要。我国行业标准QB/T 1978-2004《染发剂》中对这几中重金属元素的使用限量均作了明确的规定。近年抽查发现染发剂中铅、砷、汞不合格的情况比较少见。

 

2、对苯二胺。对苯二胺在染发剂中是中间剂,通过与头发蛋白、氧化剂与偶合剂作用,使合成的有色染料分子附着在头发上,使头发着色。而根据我国行业标准QB/T 1978-2004《染发剂》的规定,对苯二胺为限用物质。而近年的监督抽查中发现,有个别企业为了追求高额利润使用间苯二胺作为中间体。虽然间苯二胺有染发的作用,但是其是一种国际公认的三致物质,可引起致突变作用、致癌作用和致畸作用。在我国2007年版的 《化妆品卫生规范》中已被列为禁用物质。对苯二胺和间苯二胺均属于苯类添加剂,苯二胺类属于有毒成分,并且是染发剂中不可缺少的成分,故国家严格规定了使用量,并建议不宜频繁使用。

3pH值。人的皮肤和头发都是弱酸性接近于中性的,染发剂pH值过高或过低会刺激使用者的皮肤和头发,造成皮肤和头发表面酸碱度的不正常,降低皮肤抗病菌的能力。另外,碱性过强还会使头发枯黄、无光泽或断裂。因此,染发剂产品的pH值与其质量密切相关。

4、过氧化氢。也叫做显色剂或氧化剂。这一原料具有不同的形式和强度,它可以催化颜色形成和产生更持久的颜色。显色剂用量越大,就会从头发上除去越多的硫。头发没有了硫,就会变硬变轻。因此,长期使用会使头发变得枯黄、分叉,甚至会严重脱发。造成发质严重下降,头发将无法再恢复到健康的状态。GB 7916《化妆品卫生标准》中对过氧化氢在美发类产品中的使用限量作了明确规定。

5、氨水。大多数氧化型染发剂都有很大的刺激味这是因为大部份的碱化剂使用的都是氨水,氧化型染发剂的pH值为8.5-10.5,因此对碱含量有一定的要求。在染发过程中,碱含量偏高头发易膨胀有利于染料中间体对头发的渗透,碱性偏低氧化反应进行不完全引起染色效果减弱,染色不均匀、不饱满。但氨水毕竟是一种碱性物质,长期接触可出现皮肤色素沉积或手指溃疡等症状。氨水可以通过头皮毛囊进入人体,长期使用会对人体健康造成比较大危害。因此在我国标准GB 7916《化妆品卫生标准》中就对氨水的使用限量作了明确规定。

 

选购提示

1、必须有中华人民共和国卫生部特殊用途化妆品批准文号、卫生许可证号、正规的生产批号,没有的产品属于违规产品,消费者不要购买。

  2、尽量购买知名品牌。现在,染发剂的生产厂家很多,品牌也多种多样,一些规模小的生产企业在质量控制方面可能会存在一些问题,而大企业知名品牌的染发剂质量控制比较严格,所以消费者在购买时应尽量购买大厂家知名品牌的染发用品。

  3、标识清楚完整。购买染发剂要到正规的大商场或超市,购买包装完好的产品。产品的标识要清楚,除了生产批号和卫生许可证号外,产品的生产厂家、生产地址、产品名称、生产日期、安全警告、使用指南、满足保质期和安全性要求的储存条件等,都要标示清楚。

  4、区分不同性质的染发剂。现在,市场上有原料成分从天然植物中提取的染发剂,这些染发剂毒性相对较小,过敏的发生率也比较低,但是染发的颜色较浅、坚持的时间较短。化学染发剂中含有对苯二胺,效果相对较好,但是容易引起过敏,而且长期使用对肝脏有危害。所以,在购买时,消费者要注意权衡利弊。

  另外,我们在使用染发剂时,一要注意在使用前做一下实验,用少量的染发剂涂在耳后,看是否有刺激反应,如果有就应该避免使用;二是使用染发剂的次数不宜过多,应该尽量减少使用的次数或延长使用的间隔时间,这样也可以减少皮肤炎症的发生。


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